5.3.1. Determining Free Space
You can use the pvscan command to determine how much free space is currently available in the volume group.
[root@tng3-1 ~]# pvscan
PV /dev/sda1 VG myvg lvm2 [17.15 GB / 0 free]
PV /dev/sdb1 VG myvg lvm2 [17.15 GB / 12.15 GB free]
PV /dev/sdc1 VG myvg lvm2 [17.15 GB / 15.80 GB free]
Total: 3 [51.45 GB] / in use: 3 [51.45 GB] / in no VG: 0 [0 ]