CentOS

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Initializing NSS with certpath: sql:/etc/pki/nssdb
* Unable to initialize NSS database
* Initializing NSS with certpath: none
* Unable to initialize NSS
* Closing connection 0 

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$ch = curl_init();
curl_setopt($ch, CURLOPT_SSL_VERIFYPEER, 0);
//curl_setopt($ch,CURLOPT_SSL_VERIFYPEER, false);
curl_setopt($ch, CURLOPT_SSL_VERIFYHOST, 0);
//curl_setopt($ch, CURLOPT_CAINFO, 'cacert.pem');
curl_setopt($ch, CURLOPT_SSLVERSION, 3);
curl_setopt($ch, CURLOPT_URL, $url);
curl_setopt($ch, CURLOPT_HEADER, FALSE);
curl_setopt($ch, CURLOPT_RETURNTRANSFER, TRUE);
$returnInfo = curl_exec($ch); 

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php -i | grep SSL
SSL => Yes
SSL Version => NSS/3.28.4
PHP Warning: Unknown: It is not safe to rely on the system's timezone settings. You are *required* to use the date.timezone setting or the date_default_timezone_set() function. In case you used any of those methods and you are still getting this warning, you most likely misspelled the timezone identifier. We selected the timezone 'UTC' for now, but please set date.timezone to select your timezone. in Unknown on line 0
OpenSSL support => enabled
OpenSSL Library Version => OpenSSL 1.0.2k-fips 26 Jan 2017
OpenSSL Header Version => OpenSSL 1.0.2k-fips 26 Jan 2017
Native OpenSSL support => enabled