The instructions from @deajan should work if you follow them. The part about "boot into sys rescue cd graphic and get gparted to wipe your hard disk partition layout." is key for you.
dd if=/dev/zero of=/dev/sda bs=512 count=64
Edit... On a side note, you could keep CentOS and run xp as a virtual machine with VirtualBox, vmware or xen.
Guess we can thank the VAX/VMS (now there was an OS!)
from the defunct Digital Equipment Corp
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